King, David, Watts, Michael, Hamilton, Elliott, Mortimer, Robert ORCID: https://orcid.org/0000-0003-1292-8861, Coffey, Michael, Osano, Odipo and Di Bonito, Marcello (2024) Mercury speciation in environmental samples associated with artisanal small-scale gold mines using a novel solid-phase extraction approach to sample collection and preservation. Environmental Geochemistry and Health. (In Press)

	Text Manuscript_King et al_edited version3 for IPR.pdf - Accepted Version Restricted to Repository staff only Download (1MB)
	Text Manuscript_King et al_edited version3 for IPR.docx - Accepted Version Restricted to Repository staff only Download (5MB)
	Text Supplementary Figures.docx - Accepted Version Restricted to Repository staff only Download (215kB)
	Spreadsheet Copy of Supplementary Tables.xlsx - Accepted Version Restricted to Repository staff only Download (73kB)

Abstract

In artisanal small-scale gold mines (ASGM), mercury (Hg) is known to pollute nearby river waters and sediments where it can be methylated to the highly bioavailable methylmercury (MeHg). The assessment of Hg speciation in water samples has been challenging for many years, with recommended procedures often not adequately allowing for analysis of samples in a suitable timeframe. Using a novel solid-phase extraction (SPE) method for sampling and preservation of Hg species, representative speciation data can be safely and easily collected and retained for up to 4-weeks (MeHg = 115 ± 8% refrigerated and 109 ± 13% unrefrigerated storage; Hg2+ = 100 ± 14% refrigerated and 94 ± 12% unrefrigerated storage). Concentrations of MeHg in environmental water samples and drinking water were below detection limit across two ASGM sites in western Kenya and concentrations of Hg2+ were below drinking water guidelines; however, drinking water sources contribute 20 – 30% of the tolerable weekly intake of Hg, indicating a need to minimise exposure of Hg from dietary sources to prevent Hg poisoning. Sediments from receiving rivers at ASGM sites showed total Hg concentrations above guideline limits (0.08 – 1.84 mg kg-1 total Hg) along the length of the river; however, MeHg concentrations fluctuated dependent on the stagnation of the river due to damns and ponds (5.9 ± 14.3 µg kg-1 MeHg). The findings show that SPE can be used as a robust sample collection and preservation approach for Hg speciation, which can better inform mitigation measures, understand ecological and human health implications, and improve environmental monitoring.

Item Type:	Article
Status:	In Press
School/Department:	Vice Chancellor's Office
URI:	https://ray.yorksj.ac.uk/id/eprint/10585

University Staff: Request a correction | RaY Editors: Update this record